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Chromogenic, specific detection of the nerve-agent mimic DCNP (a Tabun mimic)

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Chemistry - A European Journal

Abstract

Nerve-gas detection: An azo dye with pyridine and aniline moieties can selectively detect diethylcyanophosphonate (DCNP) from diisopropylfluorophosphate (DFP) and diethylchlorophosphate (DCP) by colour changes. Upon addition of DFP and DCP a phosphorylation in the pyridine occurs with a colour change from orange to magenta, whereas addition of DCNP phosphorylated the aniline ring with a colour change from orange to yellow (see figure). Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.