Abstract
The influence of an accelerated hygrothermal ageing simulation test on a commercial PLA and its three
subsequent mechanically-reprocessed materials was studied. The analysis was focused on the water
diffusion kinetics and the physico-chemical changes induced by the hygrothermal degradation. Water
diffusion proceeded faster than chain relaxation processes, as defined by a Case II absorption model. It
was proved that the water diffusion rate decreased with subsequent reprocessing cycles and increased
with higher hygrothermal ageing temperatures. Hydrolytic chain scission provoked significant molar
mass decays and consequent general losses of thermal and mechanical performance. The rearrangement
into crystalline fractions of shorter chains provoked by hygrothermal ageing was qualitatively and
quantitatively followed by both Fourier-Transform Infrared Spectroscopy and Differential Scanning
Calorimetry. The microstructural changes were monitored by the cold-crystallization temperature, the
crystallinity degree XC and the absorbance intensity ratio I921/I955. A Weibull model showed that the
crystallites were formed faster at higher reprocessing cycles and at lower hygrothermal ageing
temperatures. All these effects were particularly significant for PLA reprocessed more than one time.
